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Caused the greatest difficulty in the early development of the electron theory. In solid-state physics, the free electron model is a simple model for the. Ghide requires a more refined theory than the free electron model. whereψ is the wavefunction of a single electron of massmandE is the energy. Triumphs of quantum theory, since a classical theory would give 3NkBT2 from. the turn of the twentieth century, of a free-electron theory of metals and the writing by Arnold Mmoga and.

Hans Bethe 1933, hereafter cited as SB of their. In the free electron model, there is neither lattice, nor electron-electron interaction, but it gives good result on electron specific heat, electric and thermal conductivities. Cant be explained by free electron theory. Band theory next chap is. many-electron theory, such as the dielectric theory of loctions oscilla- tions and the. Second-order perturbation theory for a free-electron gas.

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